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Issue 14, 2012
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Organic ionic plastic crystal-based electrolytes for solid-state dye-sensitized solar cells

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Abstract

An organic ionic plastic crystal, 1-ethyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl) imide (P12TFSI), was synthesized and doped with a room temperature ionic liquid, 1-propyl-3-methylimidazolium iodide (PMII). The prepared PMII/P12TFSI solid-state electrolytes were employed for dye-sensitized solar cells (DSSCs), without using any volatile organic solvent. The fabricated solid-state DSSCs yielded a power conversion efficiency of 5.12% under simulated air mass 1.5 solar spectrum illuminations at 50 mW cm−2. The superior long-term stability of the fabricated solid-state DSSCs indicated that the synthesized PMII/P12TFSI solid-state electrolytes could overcome the drawbacks of cells containing volatile solvents.

Graphical abstract: Organic ionic plastic crystal-based electrolytes for solid-state dye-sensitized solar cells

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Publication details

The article was received on 26 Dec 2011, accepted on 06 Feb 2012 and first published on 24 Feb 2012


Article type: Paper
DOI: 10.1039/C2JM16850B
J. Mater. Chem., 2012,22, 6674-6679

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    Organic ionic plastic crystal-based electrolytes for solid-state dye-sensitized solar cells

    Q. Li, X. Chen, J. Zhao, L. Qiu, Y. Zhang, B. Sun and F. Yan, J. Mater. Chem., 2012, 22, 6674
    DOI: 10.1039/C2JM16850B

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