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Issue 20, 2012
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Synthetic routes toward MOF nanomorphologies

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Abstract

As metal–organic frameworks (MOFs) are coming of age, their structural diversity, exceptional porosity and inherent functionality need to be transferred into useful applications. Fashioning MOFs into various shapes and at the same time controlling their size constitute an essential step toward MOF-based devices. Moreover, downsizing MOFs to the nanoscale triggers a whole new set of properties distinguishing nanoMOFs from their bulk counterparts. Therefore, dimensionality-controlled miniaturization of MOFs enables the customised use of nanoMOFs for specific applications where suitable size and shape are key prerequisites. In this feature article we survey the burgeoning field of nanoscale MOF synthesis, ranging from classical protocols such as microemulsion synthesis all the way to microfluidic-based techniques and template-directed epitaxial growth schemes. Along these lines, we will fathom the feasibility of rationally designing specific MOF nanomorphologies—zero-, one- and two-dimensional nanostructures—and we will explore more complex “second-generation” nanostructures typically evolving from a high level of interfacial control. As a recurring theme, we will review recent advances made toward the understanding of nucleation and growth processes at the nanoscale, as such insights are expected to further push the borders of nanoMOF science.

Graphical abstract: Synthetic routes toward MOF nanomorphologies

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Article information


Submitted
05 Nov 2011
Accepted
17 Jan 2012
First published
10 Feb 2012

J. Mater. Chem., 2012,22, 10119-10133
Article type
Feature Article

Synthetic routes toward MOF nanomorphologies

E. A. Flügel, A. Ranft, F. Haase and B. V. Lotsch, J. Mater. Chem., 2012, 22, 10119
DOI: 10.1039/C2JM15675J

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