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Issue 26, 2012
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A heterobimetallic metal–organic framework with tunable reactive metal sites: synthesis, characterization, and reactivity

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Abstract

A technique for preparing heterobimetallic frameworks with tunable metal sites is demonstrated by the synthesis of a new two-dimensional metal–organic framework that is constructed from tetra(4-carboxyphenyl)porphyrin and Cd(II) species. The solid can be prepared in the presence of other divalent transition metals to yield the same framework with the smaller metal ions occupying the porphyrin ligands.

Graphical abstract: A heterobimetallic metal–organic framework with tunable reactive metal sites: synthesis, characterization, and reactivity

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Article information


Submitted
25 Jan 2012
Accepted
05 Mar 2012
First published
09 Mar 2012

Dalton Trans., 2012,41, 7855-7858
Article type
Communication

A heterobimetallic metal–organic framework with tunable reactive metal sites: synthesis, characterization, and reactivity

N. C. Smythe, D. P. Butler, C. E. Moore, W. R. McGowan, A. L. Rheingold and L. G. Beauvais, Dalton Trans., 2012, 41, 7855
DOI: 10.1039/C2DT30184A

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