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Issue 17, 2012
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Synthesis, structure and reactivity of 4-phosphanylated 1,3-dialkyl-imidazole-2-thiones

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Abstract

Selective formation of 4-phosphanylated 1,2-dialkyl imidazole-2-thiones 3a–f has been obtained via a lithiation followed by phosphanylation reaction. The reactivity of 3a–f was examined towards oxidation and complexation reactions. All products were unambiguously characterized by elemental analyses, spectroscopic and spectrometric methods including X-ray analysis (3a, 3b, 4b, 4d, 5b, 6a and 6d).

Graphical abstract: Synthesis, structure and reactivity of 4-phosphanylated 1,3-dialkyl-imidazole-2-thiones

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Article information


Submitted
23 Dec 2011
Accepted
13 Feb 2012
First published
13 Feb 2012

Dalton Trans., 2012,41, 5368-5376
Article type
Paper

Synthesis, structure and reactivity of 4-phosphanylated 1,3-dialkyl-imidazole-2-thiones

S. Sauerbrey, P. K. Majhi, G. Schnakenburg, A. J. Arduengo III and R. Streubel, Dalton Trans., 2012, 41, 5368
DOI: 10.1039/C2DT12483A

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