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Issue 11, 2012
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Unusual electronic structure of bis-isocyanide complexes of iron(III) porphyrinoids

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Abstract

A series of isocyanide complexes, [Fe(Porphyrinoid)(tBuNC)2]+, were synthesized and examined for their physicochemical properties. The molecular structure of the bis(tBuNC) adduct of the iron(III) porphycene (1) and corrphycene (2) adopting the (dxy)2(dxz, dyz)3 ground state were determined for the first time. Furthermore, 1 and 2 showed unusual crossover phenomena between different electron configurations, (dxy)2(dxz, dyz)3 ground state and (dxz, dyz)4(dxy)1 ground state, by the addition of the external stimuli.

Graphical abstract: Unusual electronic structure of bis-isocyanide complexes of iron(iii) porphyrinoids

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Publication details

The article was received on 23 Nov 2011, accepted on 06 Jan 2012 and first published on 06 Feb 2012


Article type: Communication
DOI: 10.1039/C2DT12249A
Dalton Trans., 2012,41, 3126-3129

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    Unusual electronic structure of bis-isocyanide complexes of iron(III) porphyrinoids

    Y. Ohgo, S. Neya, D. Hashizume, T. Ozeki and M. Nakamura, Dalton Trans., 2012, 41, 3126
    DOI: 10.1039/C2DT12249A

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