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Issue 41, 2012
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Wavelength dependent photocatalytic H2 generation using iridium–Pt/Pd complexes

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Abstract

Novel cyclometallated iridium–Pt/Pd dinuclear complexes containing the bridging ligand 2,2′:5′,2′′-terpyridine (BPP) and the peripheral phenylpyridine (ppy) ligand produced hydrogen under both visible (470 nm) and UV (350 nm) irradiation. The turnover numbers using visible light were found to be significantly higher, indicating an interplay between two independent excited states, only one of which produces H2 efficiently.

Graphical abstract: Wavelength dependent photocatalytic H2 generation using iridium–Pt/Pd complexes

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Supplementary files

Article information


Submitted
29 Aug 2012
Accepted
04 Sep 2012
First published
06 Sep 2012

Dalton Trans., 2012,41, 12678-12680
Article type
Communication

Wavelength dependent photocatalytic H2 generation using iridium–Pt/Pd complexes

S. Soman, G. Singh Bindra, A. Paul, R. Groarke, J. C. Manton, F. M. Connaughton, M. Schulz, D. Dini, C. Long, M. T. Pryce and J. G. Vos, Dalton Trans., 2012, 41, 12678
DOI: 10.1039/C2DT32028B

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