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Issue 44, 2012
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Multi-frequency EPR studies of a mononuclear holmium single-molecule magnet based on the polyoxometalate [HoIII(W5O18)2]9−

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Abstract

Continuous-wave, multi-frequency electron paramagnetic resonance (EPR) studies are reported for a series of single-crystal and powder samples containing different dilutions of a recently discovered mononuclear HoIII (4f10) single-molecule magnet (SMM) encapsulated in a highly symmetric polyoxometalate (POM) cage. The encapsulation offers the potential for applications in molecular spintronics devices, as it preserves the intrinsic properties of the nanomagnet outside of the crystal. A significant magnetic anisotropy arises due to a splitting of the Hund's coupled total angular momentum (J = L + S = 8) ground state in the POM ligand field. Thus, high-frequency (50.4 GHz) EPR studies reveal a highly anisotropic eight line spectrum corresponding to transitions within the lowest mJ = ±4 doublet, split by a strong hyperfine interaction with the I = 7/2 Ho nucleus (100% natural abundance). X-band EPR studies reveal the presence of an appreciable tunneling gap between the mJ = ±4 doublet states having the same nuclear spin projection, leading to a highly non-linear field-dependence of the spectrum at low-frequencies.

Graphical abstract: Multi-frequency EPR studies of a mononuclear holmium single-molecule magnet based on the polyoxometalate [HoIII(W5O18)2]9−

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Article information


Submitted
25 Jul 2012
Accepted
21 Aug 2012
First published
22 Aug 2012

Dalton Trans., 2012,41, 13697-13704
Article type
Paper

Multi-frequency EPR studies of a mononuclear holmium single-molecule magnet based on the polyoxometalate [HoIII(W5O18)2]9−

S. Ghosh, S. Datta, L. Friend, S. Cardona-Serra, A. Gaita-Ariño, E. Coronado and S. Hill, Dalton Trans., 2012, 41, 13697
DOI: 10.1039/C2DT31674A

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