Issue 26, 2012
From the journal:

Dalton Transactions

Conversion of {Fe(NO)2}10 dinitrosyl iron to nitrato iron(iii) species by molecular oxygen†

Kelsey M. Skodje,a   Paul G. Williarda  and  Eunsuk Kim*a  

* Corresponding authors

a Department of Chemistry, Brown University, Providence, RI 02912, USA
E-mail: eunsuk_kim@brown.edu

Abstract

A new {Fe(NO)2}10 dinitrosyl iron complex possessing a 2,9-dimethyl-1,10-phenanthroline ligand has been prepared. This complex exhibits dioxygenase activity, converting NO to nitrate (NO3−) anions. During the oxygenation reaction, formation of reactive nitrating species is implicated, as shown in the effective o-nitration with a phenolic substrate.

Graphical abstract: Conversion of {Fe(NO)2}10 dinitrosyl iron to nitrato iron(iii) species by molecular oxygen

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Article information

DOI
https://doi.org/10.1039/C2DT30443K
Article type
Communication
Submitted
23 Feb 2012
Accepted
03 Apr 2012
First published
11 Apr 2012

Dalton Trans., 2012,41, 7849-7851

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Conversion of {Fe(NO)2}10 dinitrosyl iron to nitrato iron(III) species by molecular oxygen

K. M. Skodje, P. G. Williard and E. Kim, Dalton Trans., 2012, 41, 7849 DOI: 10.1039/C2DT30443K

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