Issue 5, 2012
From the journal:

Catalysis Science & Technology

Catalytic epoxidation of styrene and methyl oleate over peroxophosphotungstate entrapped in mesoporous SBA-15†

Evelyne Poli,a   Rodolphe De Sousa,a   François Jérome,a   Yannick Pouillouxa  and  Jean-Marc Clacens*ab  

* Corresponding authors

a Institut de Chimie des Milieux et Matériaux de Poitiers, CNRS (UMR 7285), 4 rue Michel Brunet, 86022 Poitiers, France
E-mail: jean-marc.clacens@univ-poitiers.fr
Fax: +33 54945 3779
Tel: +33 54945 4417

b Eco-Efficient Products and Processes Laboratory, Rhodia–CNRS (UMI 3464), 3966 Jin Du Rd., Xin Zhuang Industrial Zone, Shanghai 201108, China
E-mail: jeanmarc.clacens-ext@ap.rhodia.com
Fax: +86 21 54425911
Tel: +86 21 24089267

Abstract

A new route for the heterogenization of peroxophosphotungstate species was developed for the epoxidation of olefins such as styrene and methyl oleate with hydrogen peroxide. The polyoxometalate based catalyst was entrapped inside the pores of a mesoporous SBA-15 support thanks to the grafting of octyl groups at the pores entrance allowing their convenient recycling.

Graphical abstract: Catalytic epoxidation of styrene and methyl oleate over peroxophosphotungstate entrapped in mesoporous SBA-15

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Article information

DOI
https://doi.org/10.1039/C2CY20082A
Article type
Communication
Submitted
13 Feb 2012
Accepted
07 Mar 2012
First published
09 Mar 2012

Catal. Sci. Technol., 2012,2, 910-914

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Catalytic epoxidation of styrene and methyl oleate over peroxophosphotungstate entrapped in mesoporous SBA-15

E. Poli, R. De Sousa, F. Jérome, Y. Pouilloux and J. Clacens, Catal. Sci. Technol., 2012, 2, 910 DOI: 10.1039/C2CY20082A

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