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Issue 4, 2012
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Methyltrioxorhenium-catalysed oxidation of pseudocumene in the presence of amphiphiles for the synthesis of vitamin E

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Abstract

Vitamin E is an essential food component and antioxidant of major economic relevance. 2,3,5-Trimethyl-1,4-benzoquinone is a key intermediate in the production of vitamin E, which can now be selectively achieved through MTO-catalysed oxidation of simple and inexpensive pseudocumene (1,2,4-trimethylbenzene), in the presence of hydrogen peroxide and an appropriate amphiphile.

Graphical abstract: Methyltrioxorhenium-catalysed oxidation of pseudocumene in the presence of amphiphiles for the synthesis of vitamin E

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Publication details

The article was received on 10 Aug 2011, accepted on 06 Oct 2011 and first published on 21 Oct 2011


Article type: Communication
DOI: 10.1039/C1CY00313E
Catal. Sci. Technol., 2012,2, 722-724

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    Methyltrioxorhenium-catalysed oxidation of pseudocumene in the presence of amphiphiles for the synthesis of vitamin E

    M. Carril, P. Altmann, W. Bonrath, T. Netscher, J. Schütz and F. E. Kühn, Catal. Sci. Technol., 2012, 2, 722
    DOI: 10.1039/C1CY00313E

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