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Issue 3, 2012
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Trace metal impurities in catalysis

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Abstract

Metal-catalysed transformations are a powerful tool in organic chemistry and the enormous progress, which has been made in the last few decades, was one more time honoured by the Nobel Prize in Chemistry in 2010. Many metal-containing compounds have been applied in carboncarbon and carbon–heteroatom bond formations. However, not every component originally claimed as catalyst turned out to be the active ingredient in the end. Sometimes trace metal impurities were the actual catalytic species. In this tutorial review, we will highlight recent findings in transition metal-catalysed cross-coupling reactions and detail several reports from the past, which illustrate that “trace metal catalysis” is not a newly discovered phenomenon.

Graphical abstract: Trace metal impurities in catalysis

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Submitted
13 Sep 2011
First published
04 Jan 2012

Chem. Soc. Rev., 2012,41, 979-987
Article type
Tutorial Review

Trace metal impurities in catalysis

I. Thomé, A. Nijs and C. Bolm, Chem. Soc. Rev., 2012, 41, 979
DOI: 10.1039/C2CS15249E

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