Issue 25, 2012

Decoherence effects on superpositions of chiral states in a chiral molecule

Abstract

The superposition of chiral states of chiral molecules, as delocalized quantum states of a many-particle system, can be used for the experimental investigations of decoherence theory. In this regard, a great challenge is the precise quantification of the robustness of these superpositions against environmental effects. The methods so far proposed need the detailed specification of the internal states of the molecule, usually requiring heavy numerical calculations. Here, by using the linearized quantum Boltzmann equation and by borrowing ideas employed for analyzing other quantum systems, we present a general and simple approach, of wide applicability, which can be used to compute the dominant contribution to the decoherence rate for the superpositions of chiral states of chiral molecules, due to environmental scattering.

Graphical abstract: Decoherence effects on superpositions of chiral states in a chiral molecule

Article information

Article type
Paper
Submitted
22 Mar 2012
Accepted
26 Apr 2012
First published
27 Apr 2012

Phys. Chem. Chem. Phys., 2012,14, 9214-9218

Decoherence effects on superpositions of chiral states in a chiral molecule

M. Bahrami, A. Shafiee and A. Bassi, Phys. Chem. Chem. Phys., 2012, 14, 9214 DOI: 10.1039/C2CP40920H

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