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Issue 12, 2012
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Highly rigid and stable porous Cu(i) metal–organic framework with reversible single-crystal-to-single-crystal structural transformation

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Abstract

A simple room temperature reaction of Cu(NO3)2, and 2,3-pyrazinedicarboxylic acid (H2pyzdc) in the presence of dihydroxyfumaric acid (DHFA) resulted in the formation of a highly stable 3D Cu(I) coordination polymer, {[Cu2(pyzdc)]·0.83H2O}n where DHFA acts as a reducing agent. It possesses a 1D water filled channel along the crystallographic c direction and the framework shows reversible single-crystal-to-single-crystal structural transformation upon dehydration and rehydration.

Graphical abstract: Highly rigid and stable porous Cu(i) metal–organic framework with reversible single-crystal-to-single-crystal structural transformation

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Publication details

The article was received on 19 Dec 2011, accepted on 21 Mar 2012 and first published on 21 Mar 2012


Article type: Communication
DOI: 10.1039/C2CE06701C
CrystEngComm, 2012,14, 4153-4156

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    Highly rigid and stable porous Cu(I) metal–organic framework with reversible single-crystal-to-single-crystal structural transformation

    S. Mohapatra, H. Sato, R. Matsuda, S. Kitagawa and T. K. Maji, CrystEngComm, 2012, 14, 4153
    DOI: 10.1039/C2CE06701C

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