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Issue 6, 2012
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A pcu-type metal–organic framework based on covalently quadruple cross-linked supramolecular building blocks (SBBs): structure and adsorption properties†

Chuanqiang Li,a   Wenge Qiu,*a   Wei Shi,b   Haibin Song,b   Guangmei Bai,a   Hong He,*a   Jian Lia  and  Michael J. Zaworotkoc  
Author affiliations

* Corresponding authors

a Department of Chemical Science and Engineering, College of environmental and energy engineering, Beijing University of Technology, Beijing, China
E-mail: qiuwenge@bjut.edu.cn
Fax: +86 10-67391983
Tel: +86 10-67396588

b College of Chemistry, Nankai University, Tianjin, China
Tel: +86 22-23500305

c Department of Chemistry, University of South Florida, 4202 East Fowler Avenue, Tampa, Florida, USA
E-mail: xtal@usf.edu
Tel: +1 813-974-3451

Abstract

A flexible ligand with two 1,3-benzenedicarboxylate units has been used to construct a microporous metal–organic framework with pcu topology based on supramolecular building blocks (SBBs). The obtained Cu(II) MOF exhibits a noticeable CO2 adsorption hysteresis and a comparable methane adsorption capacity at room temperature.

Graphical abstract: A pcu-type metal–organic framework based on covalently quadruple cross-linked supramolecular building blocks (SBBs): structure and adsorption properties

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Publication details

The article was received on 18 Oct 2011, accepted on 31 Dec 2011 and first published on 26 Jan 2012


Article type: Communication
DOI: 10.1039/C2CE06384K
CrystEngComm, 2012,14, 1929-1932

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    A pcu-type metal–organic framework based on covalently quadruple cross-linked supramolecular building blocks (SBBs): structure and adsorption properties

    C. Li, W. Qiu, W. Shi, H. Song, G. Bai, H. He, J. Li and M. J. Zaworotko, CrystEngComm, 2012, 14, 1929
    DOI: 10.1039/C2CE06384K

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