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Issue 6, 2012
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A pcu-type metal–organic framework based on covalently quadruple cross-linked supramolecular building blocks (SBBs): structure and adsorption properties

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Abstract

A flexible ligand with two 1,3-benzenedicarboxylate units has been used to construct a microporous metal–organic framework with pcu topology based on supramolecular building blocks (SBBs). The obtained Cu(II) MOF exhibits a noticeable CO2 adsorption hysteresis and a comparable methane adsorption capacity at room temperature.

Graphical abstract: A pcu-type metal–organic framework based on covalently quadruple cross-linked supramolecular building blocks (SBBs): structure and adsorption properties

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Publication details

The article was received on 18 Oct 2011, accepted on 31 Dec 2011 and first published on 26 Jan 2012


Article type: Communication
DOI: 10.1039/C2CE06384K
CrystEngComm, 2012,14, 1929-1932

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    A pcu-type metal–organic framework based on covalently quadruple cross-linked supramolecular building blocks (SBBs): structure and adsorption properties

    C. Li, W. Qiu, W. Shi, H. Song, G. Bai, H. He, J. Li and M. J. Zaworotko, CrystEngComm, 2012, 14, 1929
    DOI: 10.1039/C2CE06384K

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