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Issue 83, 2012
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Sterically demanding imidazolinium salts through the activation and cyclization of formamides

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Abstract

A new protocol was developed for the synthesis of sterically demanding imidazolinium salts. This procedure was adopted for the synthesis of seven NHC salts, including ones that were demonstrated to be inaccessible using the conventional orthoformate ester type cyclization method.

Graphical abstract: Sterically demanding imidazolinium salts through the activation and cyclization of formamides

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Publication details

The article was received on 13 Jun 2012, accepted on 01 Sep 2012 and first published on 04 Sep 2012


Article type: Communication
DOI: 10.1039/C2CC36329A
Chem. Commun., 2012,48, 10352-10354

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    Sterically demanding imidazolinium salts through the activation and cyclization of formamides

    M. Tsimerman, D. Mallik, T. Matsuo, T. Otani, K. Tamao and M. G. Organ, Chem. Commun., 2012, 48, 10352
    DOI: 10.1039/C2CC36329A

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