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Issue 87, 2012
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Planarized B-phenylborataanthracene anions: structural and electronic impacts of coplanar constraint

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Abstract

Potassium and lithium salts of anionic B-phenylborataanthracenes, whose phenyl groups were fixed in a coplanar fashion, were synthesized. These compounds exhibited solvent-separated ion pair structures both in the crystalline state and in solution. Planarization of the phenyl moiety had a remarkable impact on the photophysical properties, such as the red-shifted absorption and intense fluorescence.

Graphical abstract: Planarized B-phenylborataanthracene anions: structural and electronic impacts of coplanar constraint

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Article information


Submitted
14 Aug 2012
Accepted
31 Aug 2012
First published
31 Aug 2012

Chem. Commun., 2012,48, 10715-10717
Article type
Communication

Planarized B-phenylborataanthracene anions: structural and electronic impacts of coplanar constraint

T. Kushida, Z. Zhou, A. Wakamiya and S. Yamaguchi, Chem. Commun., 2012, 48, 10715
DOI: 10.1039/C2CC35874C

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