Issue 82, 2012

A ladder type iron(ii) coordination polymer with cooperative spin transition

Abstract

Ladder type 1D coordination polymers were synthesised with the aim to improve the spin crossover properties of the iron(II) complexes following the concepts of crystal engineering. A wide hysteresis loop (34 K) was observed if rigid linkers were used. The first X-ray structure for a 1D iron(II) ladder is reported.

Graphical abstract: A ladder type iron(ii) coordination polymer with cooperative spin transition

Supplementary files

Article information

Article type
Communication
Submitted
17 Jul 2012
Accepted
26 Aug 2012
First published
28 Aug 2012

Chem. Commun., 2012,48, 10222-10224

A ladder type iron(II) coordination polymer with cooperative spin transition

W. Bauer, S. Schlamp and B. Weber, Chem. Commun., 2012, 48, 10222 DOI: 10.1039/C2CC35109A

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