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Abstract | Cited by

The “extra” electrons in colloidal n-type ZnO nanocrystals formed by aliovalent doping and photochemical reduction are compared. Whereas the two are similar spectroscopically, they show very different electron-transfer reactivities, attributable to their different charge-compensating cations (Al3+vs. H+).

Graphical abstract: Comparison of extra electrons in colloidal n-type Al3+-doped and photochemically reduced ZnO nanocrystals

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