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Issue 71, 2012
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‘One-pot’ Hammett plots: a general method for the rapid acquisition of relative rate data

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Abstract

A general ‘one-pot’ method for determining relative rates of reaction in complex mixtures has been established using free energy relationships to demonstrate its utility. Competition experiments involving as many as seven species gave relative rate constants that are in good agreement to those obtained from individual kinetic analyses.

Graphical abstract: ‘One-pot’ Hammett plots: a general method for the rapid acquisition of relative rate data

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Supplementary files

Article information


Submitted
07 Jun 2012
Accepted
23 Jul 2012
First published
24 Jul 2012

Chem. Commun., 2012,48, 8937-8939
Article type
Communication

‘One-pot’ Hammett plots: a general method for the rapid acquisition of relative rate data

H. M. Yau, A. K. Croft and J. B. Harper, Chem. Commun., 2012, 48, 8937
DOI: 10.1039/C2CC34074G

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