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Issue 70, 2012
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Targeted synthesis of a porous borazine-linked covalent organic framework

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Abstract

The first microcrystalline borazine-linked polymer, BLP-2(H), has been synthesized. BLP-2(H) crystallizes into 2D sheets that stack in an eclipsed AA fashion, has high thermal stability (∼420 °C) and high porosity (SABET = 1178 m2 g−1) and it can store up to 2.4 wt% of hydrogen at 77 K and 15 bar with isosteric heat of adsorption of 6.8 kJ mol−1.

Graphical abstract: Targeted synthesis of a porous borazine-linked covalent organic framework

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Supplementary files

Article information


Submitted
18 May 2012
Accepted
12 Jul 2012
First published
16 Jul 2012

Chem. Commun., 2012,48, 8823-8825
Article type
Communication

Targeted synthesis of a porous borazine-linked covalent organic framework

K. T. Jackson, T. E. Reich and H. M. El-Kaderi, Chem. Commun., 2012, 48, 8823
DOI: 10.1039/C2CC33583B

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