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Issue 44, 2012
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Deca-heterosubstituted corannulenes

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Abstract

The Cu(I)-catalyzed Ullmann condensation reaction between aliphatic alcohols and sym-pentachlorocorannulene provides a convenient entry to 1,3,5,7,9-pentaalkoxycorannulenes. The latter are easily converted to novel deca-heterosubstituted derivatives, such as 1,3,5,7,9-penta-X-2,4,6,8,10-penta-Y-corannulenes by electrophilic aromatic substitution.

Graphical abstract: Deca-heterosubstituted corannulenes

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Article information


Submitted
11 Mar 2012
Accepted
16 Apr 2012
First published
17 Apr 2012

Chem. Commun., 2012,48, 5425-5427
Article type
Communication

Deca-heterosubstituted corannulenes

A. Pogoreltsev, E. Solel, D. Pappo and E. Keinan, Chem. Commun., 2012, 48, 5425
DOI: 10.1039/C2CC31801F

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