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Issue 44, 2012
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Trichlorosilyl triflate-mediated enantioselective directed cross-aldol reaction between ketones using a chiral phosphine oxide as an organocatalyst

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Abstract

Trichlorosilyl triflate-promoted directed cross-aldol reaction between ketones in the presence of a chiral phosphine oxide as an organocatalyst is described. This is the first enantioselective cross-aldol reaction between simple ketones with good enantioselectivity.

Graphical abstract: Trichlorosilyl triflate-mediated enantioselective directed cross-aldol reaction between ketones using a chiral phosphine oxide as an organocatalyst

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Publication details

The article was received on 29 Feb 2012, accepted on 10 Apr 2012 and first published on 27 Apr 2012


Article type: Communication
DOI: 10.1039/C2CC31543B
Chem. Commun., 2012,48, 5524-5526

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    Trichlorosilyl triflate-mediated enantioselective directed cross-aldol reaction between ketones using a chiral phosphine oxide as an organocatalyst

    S. Aoki, S. Kotani, M. Sugiura and M. Nakajima, Chem. Commun., 2012, 48, 5524
    DOI: 10.1039/C2CC31543B

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