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Pyridine-modified COF-10 exhibits enhanced stability in humid air relative to un-modified COF-10. Solid state NMR and computational studies were used to probe the nature of pyridine interactions with the framework. We propose two models for pyridine–framework interactions with different stabilities.

Graphical abstract: Experimental and computational studies of pyridine-assisted post-synthesis modified air stable covalent–organic frameworks

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