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Issue 37, 2012
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Activation and amplification of the third-order NLO and luminescent responses of a precursor cluster by a supramolecular approach

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Abstract

Solvothermal reactions of [Et4N][Tp*WS3(CuCl)3] (1) (Tp* = hydridotris(3,5-dimethylpyrazol-1-yl)borate) with CuCN and KCu(CN)2 afforded two [Tp*WS3Cu3]-based coordination polymers [Tp*WS3Cu33-DMF){Cu(CN)3}]2 (2) and K[Tp*WS3Cu33-DMF){Cu2(CN)4.5}]2 (3). The third-order NLO and PL responses of 1 were activated and greatly amplified through its assembly via the [Cu(CN)3]2− and [Cu4(CN)9]5− species in 2 and 3.

Graphical abstract: Activation and amplification of the third-order NLO and luminescent responses of a precursor cluster by a supramolecular approach

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Article information


Submitted
26 Jan 2012
Accepted
13 Mar 2012
First published
14 Mar 2012

Chem. Commun., 2012,48, 4480-4482
Article type
Communication

Activation and amplification of the third-order NLO and luminescent responses of a precursor cluster by a supramolecular approach

X. Chen, H. Li, Z. Zhang, W. Zhao, J. Lang and B. F. Abrahams, Chem. Commun., 2012, 48, 4480
DOI: 10.1039/C2CC30581J

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