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Issue 27, 2012
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Expanding the regioselective enzymatic repertoire: oxidative mono-cleavage of dialkenes catalyzed by Trametes hirsuta

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Abstract

The first report of a biocatalytic regioselective oxidative mono-cleavage of dialkenes was successfully achieved employing a cell-free enzyme preparation from Trametes hirsuta at the expense of molecular oxygen. Selected reactions were performed on a preparative scale affording high to excellent conversions and chemoselectivities.

Graphical abstract: Expanding the regioselective enzymatic repertoire: oxidative mono-cleavage of dialkenes catalyzed by Trametes hirsuta

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Article information


Submitted
04 Dec 2011
Accepted
10 Feb 2012
First published
10 Feb 2012

Chem. Commun., 2012,48, 3303-3305
Article type
Communication

Expanding the regioselective enzymatic repertoire: oxidative mono-cleavage of dialkenes catalyzed by Trametes hirsuta

C. E. Paul, A. Rajagopalan, I. Lavandera, V. Gotor-Fernández, W. Kroutil and V. Gotor, Chem. Commun., 2012, 48, 3303
DOI: 10.1039/C2CC17572J

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