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Issue 14, 2012
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Kinetics of Zn2+ complexation by a ditopic phenanthroline-azamacrocyclic scorpiand-like receptor

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Abstract

Coordination of Zn2+ to a ditopic phenanthroline-macrocycle receptor takes place in three steps, the first one being the coordination to the phenanthroline, followed by the slow movement of the metal to the polyamine macrocycle and a final re-arrangement to coordinate the pendent arm.

Graphical abstract: Kinetics of Zn2+ complexation by a ditopic phenanthroline-azamacrocyclic scorpiand-like receptor

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Article information


Submitted
03 Nov 2011
Accepted
13 Dec 2011
First published
16 Dec 2011

Chem. Commun., 2012,48, 1994-1996
Article type
Communication

Kinetics of Zn2+ complexation by a ditopic phenanthroline-azamacrocyclic scorpiand-like receptor

J. Gonzalez, R. Gavara, O. Gadea, S. Blasco, E. García-España and F. Pina, Chem. Commun., 2012, 48, 1994
DOI: 10.1039/C2CC16831F

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