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Issue 28, 2012
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Chemical communication: conductors and insulators of screw-sense preference between helical oligo(aminoisobutyric acid) domains

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Abstract

1H NMR studies quantify the abilities of achiral amino acids to communicate a left-handed screw-sense preference from one helical Aib4 domain to another: certain quaternary amino acids (e.g. Ac6c) act as effective conductors of conformational preference while others (e.g. diphenylglycine) acts as insulators.

Graphical abstract: Chemical communication: conductors and insulators of screw-sense preference between helical oligo(aminoisobutyric acid) domains

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Article information


Submitted
04 Jan 2012
Accepted
30 Jan 2012
First published
31 Jan 2012

Chem. Commun., 2012,48, 3397-3399
Article type
Communication

Chemical communication: conductors and insulators of screw-sense preference between helical oligo(aminoisobutyric acid) domains

T. Boddaert, J. Solà, M. Helliwell and J. Clayden, Chem. Commun., 2012, 48, 3397
DOI: 10.1039/C2CC00060A

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