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Issue 69, 2012
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Charge-order driven proton arrangement in a hydrogen-bonded charge-transfer complex based on a pyridyl-substituted TTF derivative

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Abstract

A unique N+–H⋯N hydrogen-bonded (H-bonded) dimer motif based on partially oxidized pyridyl-substituted TTF was constructed in the charge-transfer complex. The charge ordering in the TTF column by the charge disproportionation in the dimer regulates the arrangement of the H-bonded proton, evidencing the proton–electron coupled state.

Graphical abstract: Charge-order driven proton arrangement in a hydrogen-bonded charge-transfer complex based on a pyridyl-substituted TTF derivative

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Article information


Submitted
15 Jun 2012
Accepted
10 Jul 2012
First published
10 Jul 2012

Chem. Commun., 2012,48, 8673-8675
Article type
Communication

Charge-order driven proton arrangement in a hydrogen-bonded charge-transfer complex based on a pyridyl-substituted TTF derivative

S. C. Lee, A. Ueda, H. Kamo, K. Takahashi, M. Uruichi, K. Yamamoto, K. Yakushi, A. Nakao, R. Kumai, K. Kobayashi, H. Nakao, Y. Murakami and H. Mori, Chem. Commun., 2012, 48, 8673
DOI: 10.1039/C2CC34296K

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