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Issue 59, 2012

Intermolecular central to axial chirality transfer in the self-assembled biphenyl containing amino acid–oxalamide gelators

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Abstract

Chiral amino acid and biphenyl incorporating oxalamide gelators 4–7 with large, 9 bond distance between chiral centres and biphenyl units have been studied. CD investigation of 4-octanol gel and the crystal structure of rac-4 reveal that efficient central to axial chirality transfer occurs by intermolecular interactions in gel and solid state assemblies.

Graphical abstract: Intermolecular central to axial chirality transfer in the self-assembled biphenyl containing amino acid–oxalamide gelators

Supplementary files

Article information


Submitted
20 Mar 2012
Accepted
30 May 2012
First published
31 May 2012

Chem. Commun., 2012,48, 7407-7409
Article type
Communication

Intermolecular central to axial chirality transfer in the self-assembled biphenyl containing amino acid–oxalamide gelators

J. Makarević, Z. Štefanić, L. Horvat and M. Žinić, Chem. Commun., 2012, 48, 7407 DOI: 10.1039/C2CC32039H

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