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Issue 46, 2012
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A long-lived photo-induced metastable state of linkage isomerization accompanied with a spin transition

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Abstract

In addition to the generally observed LIESST phenomenon, polymorph D of trans-[FeII(abpt)2(NCS)2] exhibits a long-lived photo-induced metastable state through linkage isomerization accompanied with a spin crossover transition, which is stable up to 108 K.

Graphical abstract: A long-lived photo-induced metastable state of linkage isomerization accompanied with a spin transition

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Article information


Submitted
22 Feb 2012
Accepted
20 Mar 2012
First published
20 Mar 2012

Chem. Commun., 2012,48, 5715-5717
Article type
Communication

A long-lived photo-induced metastable state of linkage isomerization accompanied with a spin transition

C. Sheu, C. Shih, K. Sugimoto, B. Cheng, M. Takata and Y. Wang, Chem. Commun., 2012, 48, 5715
DOI: 10.1039/C2CC31326J

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