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Issue 40, 2012
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Molecular chirality and chiral capsule-type dimer formation of cyclic triamidesvia hydrogen-bonding interactions

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Abstract

Chiral properties of bowl-shaped cyclic triamides bearing functional groups with hydrogen-bonding ability were examined. Chiral induction of cyclic triamide3a was observed by addition of chiral amine in solution, and chiral separation was achieved by simple crystallization to afford chiral capsule-type dimer structure of 4a.

Graphical abstract: Molecular chirality and chiral capsule-type dimer formation of cyclic triamidesvia hydrogen-bonding interactions

  • This article is part of the themed collection: Chirality
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Publication details

The article was received on 31 Dec 2011, accepted on 21 Feb 2012 and first published on 22 Feb 2012


Article type: Communication
DOI: 10.1039/C2CC18177K
Chem. Commun., 2012,48, 4809-4811

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    Molecular chirality and chiral capsule-type dimer formation of cyclic triamidesvia hydrogen-bonding interactions

    N. Fujimoto, M. Matsumura, I. Azumaya, S. Nishiyama, H. Masu, H. Kagechika and A. Tanatani, Chem. Commun., 2012, 48, 4809
    DOI: 10.1039/C2CC18177K

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