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Issue 19, 2012
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Contrasting reductions of group 14 metal(ii) chloride complexes: synthesis of a β-diketiminato tin(i) dimer

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Abstract

Reductions of the β-diketiminato group 14 metal(II) chloride complexes, [(ButMesNacnac)ECl] (ButMesNacnac = [(MesNCBut)2CH]; Mes = mesityl; E = Ge, Sn or Pb), with a magnesium(I) dimer have led to differing outcomes, which include the formation of the first β-diketiminato group 14 metal(I) dimer, [{(ButMesNacnac)Sn}2].

Graphical abstract: Contrasting reductions of group 14 metal(ii) chloride complexes: synthesis of a β-diketiminato tin(i) dimer

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Article information


Submitted
26 Dec 2011
Accepted
08 Jan 2012
First published
10 Jan 2012

Chem. Commun., 2012,48, 2504-2506
Article type
Communication

Contrasting reductions of group 14 metal(II) chloride complexes: synthesis of a β-diketiminato tin(I) dimer

S. L. Choong, C. Schenk, A. Stasch, D. Dange and C. Jones, Chem. Commun., 2012, 48, 2504
DOI: 10.1039/C2CC18086C

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