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Issue 53, 2012
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Chiroptical generation and inversion during the mirror-symmetry-breaking aggregation of dialkylpolysilanes due to limonene chirality

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Abstract

We observed the emergence and inversion of chiroptical handedness in three chiroptically silent dialkylpolysilanes during aggregation in limonenemethanol–THF tersolvents.

Graphical abstract: Chiroptical generation and inversion during the mirror-symmetry-breaking aggregation of dialkylpolysilanes due to limonene chirality

  • This article is part of the themed collection: Chirality
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Article information


Submitted
15 Dec 2011
Accepted
09 Feb 2012
First published
10 Feb 2012

Chem. Commun., 2012,48, 6636-6638
Article type
Communication

Chiroptical generation and inversion during the mirror-symmetry-breaking aggregation of dialkylpolysilanes due to limonene chirality

Y. Nakano, F. Ichiyanagi, M. Naito, Y. Yang and M. Fujiki, Chem. Commun., 2012, 48, 6636
DOI: 10.1039/C2CC17845A

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