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Issue 3, 2012
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Understanding the regioselectivity in Scholl reactions for the synthesis of oligoarenes

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Abstract

A short reaction sequence leads to oligoarene derivatives utilising a regioselective Scholl reaction for the unprecedented cyclisation to the mono-functionalised oligoarene under methanol elimination. Quantum-chemical investigations reveal the reason for the remarkably high regioselectivity.

Graphical abstract: Understanding the regioselectivity in Scholl reactions for the synthesis of oligoarenes

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Publication details

The article was received on 26 Sep 2011, accepted on 01 Nov 2011 and first published on 14 Nov 2011


Article type: Communication
DOI: 10.1039/C1CC15980A
Chem. Commun., 2012,48, 377-379

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    Understanding the regioselectivity in Scholl reactions for the synthesis of oligoarenes

    M. Danz, R. Tonner and G. Hilt, Chem. Commun., 2012, 48, 377
    DOI: 10.1039/C1CC15980A

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