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Issue 6, 2012
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On the origin of the alternating Diels–Alder reactivity in [n]dendralenes

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Abstract

G4(MP2) calculations on Diels–Alder reactions of [3]- and [4]dendralene have revealed that reactant dendralene conformer populations and closed-shell singlet bis-pericyclic transition states explain their different reactivities.

Graphical abstract: On the origin of the alternating Diels–Alder reactivity in [n]dendralenes

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Supplementary files

Article information


Submitted
02 Sep 2011
Accepted
29 Sep 2011
First published
01 Nov 2011

Chem. Commun., 2012,48, 832-834
Article type
Communication

On the origin of the alternating Diels–Alder reactivity in [n]dendralenes

M. N. Paddon-Row and M. S. Sherburn, Chem. Commun., 2012, 48, 832
DOI: 10.1039/C1CC15455A

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