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Issue 4, 2011
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Amino olefin nickel(i) and nickel(0) complexes as dehydrogenationcatalysts for amineboranes

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Abstract

A rare paramagnetic organometallic nickel(I) olefin complex can be isolated using the ligand bis(5H-dibenzo[a,d]cyclohepten-5-yl)amine. This complex and related nickel(0) hydride complexes show very high catalytic activity in the dehydrogenation of dimethylamino borane with release of one equivalent of dihydrogen.

Graphical abstract: Amino olefin nickel(i) and nickel(0) complexes as dehydrogenation catalysts for amine boranes

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Article information


Submitted
12 Sep 2010
Accepted
17 Dec 2010
First published
17 Jan 2011

Chem. Sci., 2011,2, 723-727
Article type
Edge Article

Amino olefin nickel(I) and nickel(0) complexes as dehydrogenation catalysts for amine boranes

M. Vogt, B. de Bruin, H. Berke, M. Trincado and H. Grützmacher, Chem. Sci., 2011, 2, 723
DOI: 10.1039/C0SC00483A

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