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Issue 12, 2011
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Synthesis of highly porous borazine-linked polymers and their application to H2, CO2, and CH4 storage†

Karl T. Jackson,a   Mohammad G. Rabbani,a   Thomas E. Reicha  and  Hani M. El-Kaderi*a  
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* Corresponding authors

a Department of Chemistry, Virginia Commonwealth University, Richmond, VA, United States
E-mail: helkaderi@vcu.edu
Fax: +1 804 828 8599
Tel: +1 804 828 7505

Abstract

The synthesis of highly porous borazine-linked polymers (BLPs) and their gas uptakes are reported. BLPs exhibit high surface areas up to 2866 m2 g−1 and can store significant amounts of H2 (1.93 wt%) and CO2 (12.8 wt%) at 77 K and 273 K, respectively at 1.0 bar with respective isosteric heats of adsorption of 6.0 and 25.2 kJ mol−1.

Graphical abstract: Synthesis of highly porous borazine-linked polymers and their application to H2, CO2, and CH4 storage

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Article information

https://doi.org/10.1039/C1PY00374G
Submitted
23 Aug 2011
Accepted
07 Oct 2011
First published
17 Oct 2011
Polym. Chem., 2011,2, 2775-2777
Article type
Communication
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Synthesis of highly porous borazine-linked polymers and their application to H2, CO2, and CH4 storage

K. T. Jackson, M. G. Rabbani, T. E. Reich and H. M. El-Kaderi, Polym. Chem., 2011, 2, 2775
DOI: 10.1039/C1PY00374G

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