Enhancing the rigidity of a network polymer of intrinsic microporosity by the combined use of phthalocyanine and triptycene components,

Mohammed Hashem; C. Grazia Bezzu; Benson M. Kariuki; Neil B. McKeown

doi:10.1039/C1PY00288K

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Enhancing the rigidity of a network polymer of intrinsic microporosity by the combined use of phthalocyanine and triptycene components†^,‡

Mohammed Hashem,^a C. Grazia Bezzu,^a Benson M. Kariuki^a and Neil B. McKeown*^a

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^a School of Chemistry, Cardiff University, Cardiff, UK
E-mail: mckeownnb@cardiff.ac.uk
Tel: +44 2920 875850

Abstract

By combining both triptycene and multifunctional phthalocyanine components within a polymer of intrinsic microporosity (PIM), a polymer network of apparent BET surface of 806 m² g⁻¹ was obtained that appears to possess a highly rigid structure as determined from the shape of its nitrogen adsorption isotherm, which is similar in appearance to that of a crystalline microporous material such as a zeolite.

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Article information

DOI: https://doi.org/10.1039/C1PY00288K
Article type: Communication
Submitted: 23 Jun 2011
Accepted: 17 Jul 2011
First published: 19 Aug 2011

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Polym. Chem., 2011,2, 2190-2192

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Enhancing the rigidity of a network polymer of intrinsic microporosity by the combined use of phthalocyanine and triptycene components^,

M. Hashem, C. Grazia Bezzu, B. M. Kariuki and N. B. McKeown, Polym. Chem., 2011, 2, 2190 DOI: 10.1039/C1PY00288K

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Polymer Chemistry