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Issue 10, 2011
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Influence of macromolecular characteristics of RAFT/MADIX poly(vinyl acetate)-based (co)polymers on their solubility in supercritical carbon dioxide

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Abstract

We investigated the structure–property relationships between poly(vinyl acetate)-based (co)polymers and their solubility in supercritical carbon dioxide. Building on RAFT/MADIX polymerization, key macromolecular characteristics—chain length, chain-end group and composition—of these (co)polymers were studied. Their solubility in sc-CO2 was determined by high-pressure infrared spectroscopy, thereby providing guidelines for their design.

Graphical abstract: Influence of macromolecular characteristics of RAFT/MADIX poly(vinyl acetate)-based (co)polymers on their solubility in supercritical carbon dioxide

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Supplementary files

Article information


Submitted
12 May 2011
Accepted
15 Jun 2011
First published
20 Jul 2011

Polym. Chem., 2011,2, 2222-2230
Article type
Paper

Influence of macromolecular characteristics of RAFT/MADIX poly(vinyl acetate)-based (co)polymers on their solubility in supercritical carbon dioxide

E. Girard, T. Tassaing, J. Marty and M. Destarac, Polym. Chem., 2011, 2, 2222
DOI: 10.1039/C1PY00209K

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