Issue 8, 2011
From the journal:

Polymer Chemistry

Synthesis of a linear polymer from an AB2 monomer of 1-(3-phenoxypropyl)piperidine-4-one in trifluoromethanesulfonic acid

Youko Tamura,a   Yumiko Ito,a   Yukari Segawa,a   Tomoya Higashiharaa  and  Mitsuru Ueda*a  

* Corresponding authors

a Department of Organic and Polymeric Materials, Tokyo Institute of Technology, 2-12-1-H120, O-okayama, Meguro-ku, Tokyo, Japan
E-mail: ueda.m.ad@m.titech.ac.jp
Fax: +81-3-5734-2127
Tel: +81-3-5734-2127

Abstract

A linear polymer was successfully prepared by self-polycondensation of 1-(3-phenoxypropyl)piperidine-4-one as an AB2 monomer, which was previously reported to produce a hyperbranched polymer (HBP) with 100% degree of branching (DB). Based on results of the model reaction, the DB could be controlled by changing the acidity of polymerization media.

Graphical abstract: Synthesis of a linear polymer from an AB2 monomer of 1-(3-phenoxypropyl)piperidine-4-one in trifluoromethanesulfonic acid

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Article information

DOI
https://doi.org/10.1039/C1PY00178G
Article type
Communication
Submitted
23 Apr 2011
Accepted
25 May 2011
First published
07 Jun 2011

Polym. Chem., 2011,2, 1644-1647

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Synthesis of a linear polymer from an AB2 monomer of 1-(3-phenoxypropyl)piperidine-4-one in trifluoromethanesulfonic acid

Y. Tamura, Y. Ito, Y. Segawa, T. Higashihara and M. Ueda, Polym. Chem., 2011, 2, 1644 DOI: 10.1039/C1PY00178G

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