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A novel initiator for atom transfer radical polymerization, also allowing for selective cleavage of polymer grafts, was designed and immobilized on a solid substrate. After cleavage, the initiator content was determined by utilizing Ellman's reagent and the cleaved polymer grafts were isolated and characterized by size exclusion chromatography.

Graphical abstract: Selective cleavage of polymer grafts from solid surfaces: assessment of initiator content and polymer characteristics

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