Issue 1, 2011
From the journal:

Polymer Chemistry

Formation of nanoporous materials via mild retro-Diels–Alder chemistry†

Mathias Glassner,a   James P. Blincoa  and  Christopher Barner-Kowollik*a  

* Corresponding authors

a Preparative Macromolecular Chemistry, Institut für Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology (KIT), Engesserstr. 18, Karlsruhe, Germany
E-mail: christopher.barner-kowollik@kit.edu
Web: http://www.macroarc.de
Fax: +49 721 608 5740

Abstract

Poly(styrene)-block-poly(ethylene oxide) copolymers synthesized via the combination of reversible addition fragmentation chain transfer (RAFT) polymerization and hetero Diels–Alder (HDA) cycloaddition can be cleaved in the solid state by a retro-HDA reaction occurring at 90 °C. Nanoporous films can be prepared from these polymers using a simple heating and washing procedure.

Graphical abstract: Formation of nanoporous materials via mild retro-Diels–Alder chemistry

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Article information

DOI
https://doi.org/10.1039/C0PY00267D
Article type
Communication
Submitted
18 Aug 2010
Accepted
17 Sep 2010
First published
04 Oct 2010

Polym. Chem., 2011,2, 83-87

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Formation of nanoporous materials via mild retro-Diels–Alder chemistry

M. Glassner, J. P. Blinco and C. Barner-Kowollik, Polym. Chem., 2011, 2, 83 DOI: 10.1039/C0PY00267D

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