Issue 1, 2011
From the journal:

Polymer Chemistry

Effect of monomer/oxidant mole ratio on polymerization mechanism, conductivity and spectral characteristics of mechanochemically prepared polypyrrole†

Oleg Yu. Posudievsky*a  and  Olga A. Kozarenkoa  

* Corresponding authors

a L.V. Pisarzhevsky Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, 31 prospekt Nauki, Kiev, Ukraine
E-mail: posol@inphyschem-nas.kiev.ua
Fax: +38044 525 6216
Tel: +38044 525 6672

Abstract

The effect of the composition of the initial reaction mixture – pyrrole/oxidant mole ratio – on the mechanism of mechanochemical polymerization of pyrrole was studied. Experimental evidence in favor of the chain mechanism for mechanochemical formation of the highly conducting PPy at high monomer/oxidant mole ratio was first obtained. Interrelation between polymerization mechanism and structure, conductivity and spectral characteristics of the prepared polypyrrole samples was considered.

Graphical abstract: Effect of monomer/oxidant mole ratio on polymerization mechanism, conductivity and spectral characteristics of mechanochemically prepared polypyrrole

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Article information

DOI
https://doi.org/10.1039/C0PY00212G
Article type
Paper
Submitted
07 Jul 2010
Accepted
06 Sep 2010
First published
30 Sep 2010

Polym. Chem., 2011,2, 216-220

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Effect of monomer/oxidant mole ratio on polymerization mechanism, conductivity and spectral characteristics of mechanochemically prepared polypyrrole

O. Yu. Posudievsky and O. A. Kozarenko, Polym. Chem., 2011, 2, 216 DOI: 10.1039/C0PY00212G

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