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Abstract | Cited by

The solid state photoexcitation of several triphenylmethyl-alkyl ketones resulted in the loss of CO and the exclusive formation of radical–radical combination products. Differences in reactivity suggest a stepwise mechanism with the unprecedented formation of primary and secondary radicals in some of the radical pair intermediates in the solid state.

Graphical abstract: Stable radicals during photodecarbonylations of trityl-alkyl ketones enable solid state reactions through primary and secondary radical centers

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