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Issue 9, 2011
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Enantiospecific 6π-photocyclization of atropisomeric α-substituted acrylanilides in the solid-state: role of crystalline confinement on enantiospecificity

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Abstract

Direct irradiation of optically-pure axially-chiral α-substituted acrylanilides in the crystalline state leads to 3,4-dihydro-2-quinolin-2-one photoproduct with an enantiomeric ratio of 85 : 15 while a racemic mixture of photoproduct is observed in solution.

Graphical abstract: Enantiospecific 6π-photocyclization of atropisomeric α-substituted acrylanilides in the solid-state: role of crystalline confinement on enantiospecificity

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Supplementary files

Article information


Submitted
01 Feb 2011
Accepted
22 Feb 2011
First published
23 Mar 2011

Photochem. Photobiol. Sci., 2011,10, 1380-1383
Article type
Communication

Enantiospecific 6π-photocyclization of atropisomeric α-substituted acrylanilides in the solid-state: role of crystalline confinement on enantiospecificity

A. J. Ayitou, N. Vallavoju, A. Ugrinov and J. Sivaguru, Photochem. Photobiol. Sci., 2011, 10, 1380
DOI: 10.1039/C1PP05057E

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