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Issue 6, 2012
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Direct amination of α-substituted nitroacetates using di-tert-butyl azodicarboxylate catalyzed by Hatakeyama's catalyst β-ICD

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Abstract

We report the first example of catalytic asymmetric direct amination of α-monosubstituted nitroacetates using di-tert-butyl azodicarboxylate. The simple and easily available Hatakeyama's catalyst β-ICD 11 was found to be a highly enantioselective catalyst for this reaction.

Graphical abstract: Direct amination of α-substituted nitroacetates using di-tert-butyl azodicarboxylate catalyzed by Hatakeyama's catalyst β-ICD

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Publication details

The article was received on 18 Oct 2011, accepted on 13 Dec 2011 and first published on 13 Dec 2011


Article type: Communication
DOI: 10.1039/C2OB06746C
Org. Biomol. Chem., 2012,10, 1158-1161

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    Direct amination of α-substituted nitroacetates using di-tert-butyl azodicarboxylate catalyzed by Hatakeyama's catalyst β-ICD

    C. Ji, Y. Liu, X. Zhao, Y. Guo, H. Wang and J. Zhou, Org. Biomol. Chem., 2012, 10, 1158
    DOI: 10.1039/C2OB06746C

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