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Issue 21, 2011
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Anthracene-resorcin[4]arene-based capsules: Synthesis and photoswitchable features

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Abstract

Herein we present the synthesis and the photochemical behavior of several new hemicarcerands containing anthracene units as photoactive species. By means of NMR investigations of compounds 9 and 11 the dimerization mode was revealed as a 9,10-9′,10′-dimerization, classically known from anthracene. Nevertheless only compound 11 could be converted to the opened form upon irradiation with 300 nm. Reopening of compounds 9 and 10 could not be achieved so far either by heating or by irradiation.

Graphical abstract: Anthracene-resorcin[4]arene-based capsules: Synthesis and photoswitchable features

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Publication details

The article was received on 27 Jun 2011, accepted on 05 Aug 2011 and first published on 05 Aug 2011


Article type: Paper
DOI: 10.1039/C1OB06030A
Org. Biomol. Chem., 2011,9, 7491-7499

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    Anthracene-resorcin[4]arene-based capsules: Synthesis and photoswitchable features

    S. Bringmann, R. Brodbeck, R. Hartmann, C. Schäfer and J. Mattay, Org. Biomol. Chem., 2011, 9, 7491
    DOI: 10.1039/C1OB06030A

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