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Abstract | Cited by

A facile method for the intermolecular Stetter reaction of various Michael acceptors with acetaldehyde as a biomimetic acylanion source was realized using N-heterocyclic carbene catalysis. This catalytic system has also been applied to the enantioselective Stetter reaction and resulted in moderate to good enantioselectivities for the corresponding Stetter products.

Graphical abstract: N-Heterocyclic carbene-catalysed intermolecular Stetter reactions of acetaldehyde

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