Stereoselective rearrangement of guaianolides to tricyclic δ-valerolactones†
Abstract
An unprecedented, highly stereoselective rearrangement of guaianolides, bearing a double bond at the C-6/C-6a position, to tricyclic δ-valerolactones is described.
* Corresponding authors
a
Universität Regensburg, Institut für Organische Chemie, Universitätsstr. 31, Regensburg, Germany
E-mail:
oliver.reiser@chemie.uni-regensburg.de
Fax: +49 941-943-4121
Tel: +49 941-943-4631
An unprecedented, highly stereoselective rearrangement of guaianolides, bearing a double bond at the C-6/C-6a position, to tricyclic δ-valerolactones is described.
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M. Schanderl, W. B. Jeong, M. Schwarz and O. Reiser, Org. Biomol. Chem., 2011, 9, 2543 DOI: 10.1039/C0OB00919A
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