Issue 5, 2011
From the journal:

Organic & Biomolecular Chemistry

New strategy to construct fused/bridged/spiro carbocyclic scaffolds based on the design of novel 6-C synthon precursor†

Jia Liu,ab   Xi Wang,b   Chang-Liang Sun,b   Bi-Jie Li,b   Zhang-Jie shib  and  Min Wang*a  

* Corresponding authors

a Department of Applied Chemistry, China Agricultural University, Beijing 100193, PR China
E-mail: wangmin@cau.edu.cn
Tel: 86-010-62731356

b Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, Peking University, Beijing, PR China
E-mail: zshi@pku.edu.cn
Fax: 86-010-62760890
Tel: 86-010-62760890

Abstract

In this article we report a new strategy to build fused/spiro/bridged carbocyclic systems with a novel 6-C synthon from readily available diallyl diacetates through the sequential Pd-catalyzed double allyl alkylation and Diels–Alder annulation. Further exploration on the application of this strategy can construct useful complex scaffolds.

Graphical abstract: New strategy to construct fused/bridged/spiro carbocyclic scaffolds based on the design of novel 6-C synthon precursor

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Article information

DOI
https://doi.org/10.1039/C0OB00660B
Article type
Paper
Submitted
03 Sep 2010
Accepted
22 Nov 2010
First published
17 Jan 2011

Org. Biomol. Chem., 2011,9, 1572-1577

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New strategy to construct fused/bridged/spiro carbocyclic scaffolds based on the design of novel 6-C synthon precursor

J. Liu, X. Wang, C. Sun, B. Li, Z. shi and M. Wang, Org. Biomol. Chem., 2011, 9, 1572 DOI: 10.1039/C0OB00660B

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